Abstract

The purpose of this study was to investigate the effect of initial particle size (IPS) on the environmental parameters and heavy metal speciation during sludge composting. Three piles were conducted: fine material (FM, screen underflow), coarse material (CM, oversize product), and mixed material (MM, mix FM and CM in 1:1). Results showed that the temperature trends of the three piles in different layers were highly repeatable during the thermophilic period. With the decrease of IPS, the heating rate and the highest temperature of the pile increased, the thermophilic period was prolonged, and the highest temperature area in the pile shifted to a lower layer. It also promoted the organic matter degradation, compost maturation, and nitrogen fixation effect. Composting had a good effect on the passivation of heavy metals, especially Cd, Cu, and Pb. The passivation effect on Cd and Cu was FM > CM > MM, and on Pb was CM > FM > MM. Fourier transform infrared spectroscopy, excitation-emission matrix, and thermogravimetric thermal analysis indicated that FM had the highest content of aromatic structure and humic-like substance on D40. The redundancy analysis revealed that MM was beneficial to improve the internal uniformity during composting.

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