Effects of ball-milling on lithium insertion into multi-walled carbon nanotubes synthesized by thermal chemical vapour deposition

Abstract

The effects of ball-milling on Li insertion into multi-walled carbon nanotubes (MWNTs) are presented. The MWNTs are synthesized on supported catalysts by thermal chemical vapour deposition, purified, and mechanically ball-milled by the high energy ball-milling. The purified MWNTs and the ball-milled MWNTs were electrochemically inserted with Li. Structural and chemical modifications in the ball-milled MWNTs change the insertion–extraction properties of Li ions into/from the ball-milled MWNTs. The reversible capacity ( C rev) increases with increasing ball-milling time, namely, from 351 mAh g −1 (Li 0.9C 6) for the purified MWNTs to 641 mAh g −1 (Li 1.7C 6) for the ball-milled MWNTs. The undesirable irreversible capacity ( C irr) decreases continuously with increase in the ball-milling time, namely, from 1012 mAh g −1 (Li 2.7C 6) for the purified MWNTs to 518 mAh g −1 (Li 1.4C 6) for the ball-milled MWNTs. The decrease in C irr of the ball-milled samples results in an increase in the coulombic efficiency from 25% for the purified samples to 50% for the ball-milled samples. In addition, the ball-milled samples maintain a more stable capacity than the purified samples during charge–discharge cycling.