Abstract

Austenitizing temperature is one decisive factor for the mechanical properties of medium carbon martensitic stainless steels (MCMSSs). In the present work, the effects of austenitizing temperature (1000, 1020, 1040 and 1060 °C) on the microstructure and mechanical properties of MCMSSs containing metastable retained austenite (RA) were investigated by means of electron microscopy, X-ray diffraction (XRD), as well as tensile and impact toughness tests. Results suggest that the microstructure including an area fraction of undissolved M23C6, carbon and chromium content in matrix, prior austenite grain size (PAGS), fraction and composition of RA in studied MCMSSs varies with employed austenitizing temperature. By optimizing austenitizing temperature (1060 °C for 40 min) and tempering (250 °C for 30 min) heat treatments, the MCMSS demonstrates excellent mechanical properties with the ultimate tensile strength of 1740 ± 8 MPa, a yield strength of 1237 ± 19 MPa, total elongation (ductility) of 10.3 ± 0.7% and impact toughness of 94.6 ± 8.0 Jcm−2 at room temperature. The increased ductility of alloys is mainly attributed to the RA with a suitable stability via a transformation-induced plasticity (TRIP) effect, and a matrix containing reduced carbon and chromium content. However, the impact toughness of MCMSSs largely depends on M23C6 carbides.

Highlights

  • Published: 20 February 2021Medium carbon martensitic stainless steels (MCMSSs) are commonly used for manufacturing components, such as cutlery, dental and surgical instruments, valve trim and parts, shafts, and plastic molding [1,2], due to a good combination of high strength and medium corrosion resistance

  • The austenitizing temperature plays a decisive role in the initial microstructure, including the fraction of undissolved Cr-rich carbides and austenite in matrix, which will be inherited in the final products in the following process [5]

  • The of 1060-NP, the impact toughness of 1020-P and 1040-P decreases when the volume frachigh mechanical stability of retained austenite (RA) in 1040-P is mainly attributed to its higher carbon content tion of RA increases. This indicates that the impact toughness does depend on and finer grain size, as can be seen in Figures 6b and 7e. These results indicate that the the volume fraction of RA

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Summary

Introduction

Published: 20 February 2021Medium carbon martensitic stainless steels (MCMSSs) are commonly used for manufacturing components, such as cutlery, dental and surgical instruments, valve trim and parts, shafts, and plastic molding [1,2], due to a good combination of high strength and medium corrosion resistance. The austenitizing temperature plays a decisive role in the initial microstructure, including the fraction of undissolved Cr-rich carbides and austenite in matrix, which will be inherited in the final products in the following process [5]. The austenitizing temperature exerts an important influence on the mechanical properties of MCMSSs [1,2,5,6,7,8]. Understanding the effects of austenitizing temperature is crucial for MCMSS production. The effects of austenitizing temperature on the microstructure and mechanical properties of martensitic stainless steels, being an attractive topic within academia and the industrial community, have been investigated widely, together with the quenching and tempering (Q-T) process [2,5,6]. Barlow [2] studied the effects of austenitizing temperature

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