Abstract
ZrB2–SiC–Si3N4w ceramics (ZSNw) were prepared via the hot-pressing sintering method. The bending strength and fracture toughness of ZSNw at room temperature reached to 520 ± 24 MPa and 5.2 ± 0.16 MPa m1/2, respectively. The enhancement in mechanical properties is attributed to the grain refinement and attenuation of grain boundary induced by the homogeneous distribution of Si3N4 whiskers. The oxidation resistance of ZSNw were conducted at 1500 °C in an air atmosphere. Remarkably, after 10 h of oxidation, ZSNw remained excellent strength and toughness reaching at 589 ± 26 MPa and 4.8 ± 0.12 MPa m1/2, respectively. This oxidation resistance of ZSNw was mainly attributed to the gain refinement induced by Si3N4 whiskers, which effectively reduced the voids within the ceramic matrix. Therefore, this process promoted the densification and homogenization of the SiO2 protective barriers, accompanied with hindering the inward permeation of oxygen and the outward release of oxides.
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