Effective degradation of tetracycline and real pharmaceutical wastewater using novel nanocomposites of biosynthesized ZnO and carbonized toner powder

Abstract

In this study, novel nanohybrids of biosynthesized zinc oxide (ZnO) and magnetite-nanocarbon (Fe3O4–NC) obtained from the carbonization of toner powder waste were fabricated and investigated for persulfate (PS) activation for the efficient degradation of tetracycline (TCN). The chemical and physical properties of the synthesized catalysts were analyzed using advanced techniques. ZnO/Fe3O4–NC nanohybrid with mass ratio 1:2, respectively in the presence of PS showed the highest TCN removal efficiency compared to the individual components (ZnO and Fe3O4–NC) and other nanohybrids with mass ratios of 1:1 and 2:1. The results indicated that efficient degradation of TCN could be attained at pH 3–7. The optimum operating parameters were TCN concentration of 12.8 mg/L, PS concentration of 7 Mm, and catalyst dose of 0.55 g/L. The high stability of ZnO/Fe3O4–NC (1:2) nanocomposite was assured by the slight drop in TCN degradation percentage from 97.27% to 85.45% after five successive runs under the optimum conditions and the concentrations of leached iron and zinc into the solution were monitored. The quenching experiments explored that the prevailing reactive entities were sulfate radicals. Additionally, the degradation of TCN in various water matrices was investigated, and a degradation pathway was suggested. Further, degradation of real pharmaceutical waste was conducted showing that the removal efficiencies of TCN, total organic carbon (TOC), and chemical oxygen demand (COD) were 89.79, 80.65, and 78.64% after 2 h under the optimum conditions. The effectiveness of the proposed system (ZnO/Fe3O4–NC (1:2) @ PS) for the degradation of real samples compiled from industrial effluents as well as its inexpensiveness and green nature qualify this system for the full-scale application.