Abstract
AbstractA novel hybrid porous polymer with hollow vesicle structure has been synthesized via Friedel‐Crafts alkylation reaction and solvent‐induced method. The resulting two‐dimensional networks are hierarchical porous materials with high Brunauer‐Emmett‐Teller (BET) surface area of 1582 m2 g−1. The vesicle structure directly influenced the activity and shaping the performance of the catalyst. The kinetic study reveals the special vesicle structure can enrich the substrates in a limit scope and increase the reaction rate. It has been demonstrated that the framework and morphology play a major role on the catalysts’ excellent performance in Suzuki–Miyaura cross‐coupling reaction of aryl chlorides. These findings help elucidate the mode action of the vesicle structure in the unrevealed Suzuki reaction mechanism of supports and the potential development of new morphology control catalysts.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
