Abstract
A novel blocked isocyanate crosslinker was synthesized, and its applicability was investigated for the low-temperature curing of automotive clearcoats. Various pyrazole derivatives were prepared as blocking agents in isocyanate crosslinkers, which strongly affect the deblocking and curing properties of the urethane-bonded coating systems. The thermal curing properties of clearcoat samples containing a pyrazole-based blocked isocyanate crosslinker and polyol resin were characterized under two different temperature conditions (120 and 150 °C). The decrease in the amount of hydroxyl groups in the polyol before and after curing was expressed by the change in OH stretching frequency in the Fourier transform infrared (FT-IR) spectra. The real-time rheological storage moduli of the bulk clearcoat mixtures were measured via a rotational rheometer to determine the effect of pyrazole-based blocking agents on the curing dynamics. In addition, a rigid-body pendulum tester (RPT) was employed to investigate the curing behavior in the thin film form. The nano-indentation and the nano-scratch tests were conducted to examine the surface hardness and scratch resistance characteristics of the cured clearcoat films. The results show that a low-temperature curing system of clearcoats can be realized by tuning the curing temperature and reactivity of isocyanate crosslinkers blocked with pyrazole-based substituents.
Highlights
Coatings for the outer surface of an automotive body have been steadily developed to improve their mechanical strength, chemical resistance, and gloss properties [1,2,3]
Smart coating systems having self-healing [10,11], self-cleaning [12], and light-sensitive [13,14] characteristics has been explored to achieve the specialized functionality required for automotive coating systems
FT-IR3.analysis was carried out to verify the progress of the urethane reaction between the HFUMO resin and various pyrazole-based
Summary
Coatings for the outer surface of an automotive body have been steadily developed to improve their mechanical strength, chemical resistance, and gloss properties [1,2,3]. Conventional automotive coatings protect the inner frames from corrosion or physical damage and enhance the exterior aesthetics of the automotive. They consist of multiple layers, including electrocoats, primers, basecoats, and clearcoats [4,5,6]. It is very important to properly develop clearcoats to impart desired characteristics, which sufficiently can satisfy the current industrial and environmental standards
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