Effect of thermal ageing on physical properties of MX80 bentonite under high-temperature conditions

Abstract

In a deep geological repository (DGR) system, the buffer layer is indispensable to ensuring the safe disposal of high-level radioactive nuclear waste (HLW). Because the heat generated by the decay of the spent nuclear fuel in a canister is released to the surrounding buffer layers, the bentonite buffer material experiences long-term high-temperature conditions. Therefore, the variations in physical properties of bentonite buffer material under high-temperature conditions are one of the important parameters in the DGRs for HLW. A series of tests on the specific gravity, specific surface area (SSA), Atterberg's limits, and free swelling ratio of MX80 bentonite after heating for different times at a high temperature of 200 °C were conducted, to investigate the influence of thermal ageing time on its physical properties. Then, the microscopic investigations, including X-ray diffraction (XRD), thermogravimetric analysis (TGA), and scanning electron microscopy (SEM), were conducted to explain the aforementioned variations from the microscopic point of view. Based on the crystal layer structure characteristics of montmorillonite, the quantitative relationships between the physical properties of bentonite and its mineral composition or bound water content were established to further explain the mechanism by which thermal ageing affects the physical properties of MX80 bentonite. The results indicate that with increasing heating time, the specific gravity, SSA, liquid limit, plastic limit, plastic index and free swelling ratio decrease sharply by 2.5%, 4.5%, 3.1%, 5.5%, 2.8% and 30.2%, respectively, within 15–30 days of heating. After 30 days of heating, their variations are negligible. Under high-temperature conditions, the transformation of mineral composition, desorption of bound water, and changes in the micro-morphology are the fundamental reasons for the variations in the physical properties of bentonite, and they influence and interact with each other.