Abstract
This study explores the impact of epoxidized palm oil (EPO) content and surfactant type on the mechanical properties of polyurethane foams. The resilience, hardness, and compressive strength of the foams were systematically analyzed at different NCO/OH molar ratios. The findings revealed that increasing EPO content generally decreased both hardness and resilience values, indicating enhanced viscoelastic properties due to the plasticizing effect of EPO's hydrocarbon chains. However, specific surfactants significantly influenced these mechanical properties. Concentrol STB PU-2254 and Tegostab® B82001 VE surfactants enhanced compressive strength by promoting a compact cellular structure with smaller, more numerous cells, effectively distributing loads and counteracting the softening effect of high EPO content. Conversely, the use of Tegostab® B8462 resulted in reduced hardness due to increased porosity from larger cell formation. At an NCO/OH ratio of 1.0, higher pMDI content improved compressive strength by increasing hard segment formation. These results underscore the importance of surfactant selection and NCO/OH ratio optimization in tailoring the mechanical properties of polyurethane foams, offering valuable insights for their application-specific design and optimization.
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