Effect of Surfactant Adsorption on the Wettability Alteration of Gas-Bearing Shales

Abstract

Abstract Water loss in low permeability reservoirs during hydraulic fracturing well completions typically results in a decrease in natural gas production due to capillary trapping near the fractures. Shale gas reservoirs, however, have shown a trend of improved gas production with increased loss of completion fluids to the shale. This nonintuitive relationship between water imbibition and enhanced gas production in shale gas reservoirs is explored here through investigation of shale wettability alteration after exposure to two surfactants, one cationic and one anionic, commonly used in hydraulic fracturing fluids. Wettability alteration of samples from two unconventional natural gas reservoirs, the Marcellus and Collingwood shales, was examined in this study. In addition to individual surfactant solutions, 1:1 mixtures of cationic and anionic surfactants were examined at concentrations above and below critical micelle concentration levels. This study provides deeper understanding of adsorption mechanisms ...