Effect of surface mechanical treatment on the oxidation behavior of FeAl-model alloy

Abstract

Fe-based alloys are commonly used in almost every sector of human life. For different reasons, the surfaces of the real parts are prepared using different methods, e.g., mirror-like polishing, grit-blasting, etc. The purpose of the present work is to answer the question how the surface preparation influences the oxidation behavior of Fe-based alloys. To answer this question, a high-purity model alloy, Fe–5 wt%Al, was isothermally oxidized in a thermogravimetrical furnace. The post-exposure analysis included SEM/EDS (WDS) and XRD. The surface roughness was determined by a contact and laser profilometer. The obtained results demonstrate that the mechanical surface preparation influences oxidation kinetics as well as the microstructure of the oxide scale formed on the alloy at both studied temperatures. Namely, polishing and grinding caused local formation of Fe-rich nodules and sub-layer of protective Al2O3. In contrast, grit-blasting leads to the formation of a thick outer Fe-oxide and internal aluminum nitridation. A significant increase in the oxidation rate of the material after grit-blasting was attributed to grain refinement in the near-surface region, resulting in an increase in easy diffusion paths, namely grain boundaries.