Abstract

In the present study, a graded ethanol precipitation technique was employed to obtain hemicelluloses from the alkali-extracted corncob liquid. The relationship between the structural characteristics of alkali-soluble corncob hemicelluloses and the production of furfural was investigated by a heterogeneous process in a biphasic system. Results showed that alkali-soluble corncob hemicelluloses mainly consisted of glucuronoarabinoxylans and l-arabino-(4-O-methylglucurono)-d-xylans, and the drying way had less influence on the sugar composition, molecular weights and the functional groups of hemicelluloses obtained by the different ethanol concentration precipitation except for the thermal property, the amorphous structure and the ability for the furfural production. Furthermore, alkali-soluble corncob hemicelluloses with higher xylose content, lower branch degree, higher polydispersity and crystallinity contributed to the furfural production. A highest furfural yield of 45.41% with the xylose conversion efficiency of 99.06% and the furfural selectivity of 45.84% was obtained from the oven-dried hemicelluloses precipitated at the 30% (v/v) ethanol concentration.

Full Text
Paper version not known

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call

Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.