Abstract
The effect of silver nanoplate (AgPL) on the singlet exciton fission (SF) of rubrene (Rub) was verified by examining the magnetic field effects (MFEs) on the SF of Rub through measuring magnetic field dependence of fluorescence intensity of Rub in two thick Rub polymer-composite films in the absence and the presence of AgPL. The fluorescence intensity of Rub in the Rub-AgPL polymer-composite film was larger than that in the Rub polymer-composite film. The enhancement (1.4 times) must be caused by strong electric fields due to localized surface plasmon resonance (LSPR) of the embedded AgPL near the Rub in polymer matrix. The magnitude of the MFEs in the Rub-AgPL polymer-composite film was almost same as those in the Rub polymer-composite film. These results strongly indicate that the efficiency of SF was enhanced by the LSPR due to the embedded AgPL into the polymer matrix in the Rub-AgPL polymer-composite film.
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