Abstract
In this study, cerium oxide (CeO2−x) coatings were prepared by magnetron sputtering in a gas mixture of Ar and O2. The effect of oxygen flow ratio (fO2) on the surface morphology, wetting behavior, chemical composition, microstructure and mechanical properties of CeO2−x coating were systematically investigated. The results showed that all CeO2−x coatings exhibited smooth surfaces and similar wetting behaviors with a hydrophobic feature. The water contact angle stabilized around 100°. Surface chemistry varied with different oxygen flow ratios and the presence of excess surface lattice oxygen led to a slight decrease in hydrophobicity. X-ray diffraction (XRD) analyses showed that the coating grown in pure Ar exhibited weak crystalline peaks. While after the incorporation of oxygen, CeO2−x coatings crystallized in a cubic CeO2 phase with preferred (111) orientation, and the peak intensity gradually decreased with increasing fO2. TEM study revealed the face-centered cubic (fcc) crystalline feature of deposited coatings and obtained Fast Fourier Transformation (FFT) pattern confirmed the disordered crystalline structure among the coating deposited at 56% fO2. The hardness and elastic modulus of the coating could achieve ~18.1GPa and ~190.2GPa when deposited at 7% fO2, then decreased slightly with further increasing fO2.
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