Effect of organic amine type on the structure and properties of the complex Zn(II) salts of ethylene–methacrylic acid copolymer with organic amines

Abstract

AbstractThe complex Zn(II) salts of ethylene–methacrylic acid copolymer (EMAA) were synthesized by using various organic amines from monoamines to polyamines, from primary amines to tertiary amines, and from molecular amines to polymer amines. Thermal analyses by differential scanning calorimetry (DSC), and the measurement of stiffness, melt flow rate (MFR), and dielectric properties were employed for the complex salts. It was found that the valence, strength of base, rigidity and flexibility, and bulkiness of the organic amines affect the degree of crystalline order of the ionic crystallites, which governs the stiffness of the complex ion ionomers. The stiffness is higher for the complex salts which form the higher orderliness in the ionic aggregates. The organic amines with two or more primary aliphatic amino groups and higher boiling temperatures from more rigid ionic crystallites in the complex ion ionomers leading to the enhanced modulus. Monoamines or polyamines with amino groups attached to flexible chains such as polyether and polysiloxane scarcely develop ionic crystallites and preferentially solvate the amorphous region including ionic groups leading to the decreased modulus. These results provide us with the fundamental information to control the modulus of ionomers.