Abstract

Intergranular Stress Corrosion Cracking (IGSCC) in austenitic Stainless Steels (SS) in Boiling Water Reactor (BWR) operating conditions have been reported worldwide. Nitrogen containing Stainless Steel is used in BWRs and it can affect IGSCC behavior. In this investigation type 304L stainless steel with two different levels of nitrogen was evaluated in the sensitized and non-sensitised strain-hardened condition. Experiments were carried out in high temperature water with controlled dissolved oxygen. In the sensitised condition, the Crack Growth Rate (CGR) reduced and in the non-sensitised strain-hardened condition the CGR increased with increase in nitrogen level in SS. Transmission electron microscopic (TEM) investigations of the as-rolled SS and the SS after tensile testing at 288 °C indicated that rolling resulted in higher grain boundary strain which is a possible cause for higher CGR in the SS with higher nitrogen. Nitrogen did not have a noticeable effect on the deformation mechanism, for the SS after tensile testing at 288 °C, and the dislocation structures observed were similar for both the SS.

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