Abstract
AbstractElectron paramagnetic resonance of Mn2+ has been studied in single crystals of magnesium sulfate heptahydrate (MgSO4 · 7 H2O) at 300°K. Mn2+ was found to substitute for Mg2+ and exhibit four inequivalent magnetic complexes corresponding to the tetramolecular unit cell of MgSO4 · 7 H2O. The results are compared with those for Mn2+ in isostructural NiSO4 · 7 H2O. The observed differences in the EPR of Mn2+ in crystals of the two salts are attributed to the magnetic interaction of Ni2+ and Mn2+.
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