Abstract

This study investigated the compressive strength of hardened cement paste and the formation of Calcium Silicate Hydrate (C-S-H) with the addition of nano silica (SiO2). Compressive strength testing was performed using MTS and Forney testing machines to determine stress-strain curves and compressive strength of the materials. The hydration process and formation of C-S-H and Calcium Hydroxide (CH) was examined using Scanning Electron Microscopy (SEM) and Fourier Transform Infrared Spectroscopy (FTIR). This study also incorporates the use of vacuum curing, in comparison to that of the traditional water curing method. Results indicate an increase in compressive strength using 1, 3 and 5% of nano silica to cement replacement by volume in comparison to the control mix (without nano silica). The optimum cement replacement to yield maximum strength was of the 1% nano silica content. The formation of C-S-H increases significantly during the early testing days which correspond with the drastic increase in compressive strength. The hydration process continues to increase throughout the 56 day trails at a moderate rate. The traditional water curing method proves to be more efficient and beneficial than of the vacuum curing method. However, vacuum cured results showed only about a 5% reduction in compressive strength after 56 day tests in comparison to the water curing method.

Highlights

  • A series of chemical reactions takes place during the hydration process of cement paste

  • The main objective of this study is to investigate the effect of nano silica in cement on the hydration process of concrete over the course of 56 days

  • This study investigated the hydration process of Portland cement with increments of nano silica addition by cement replacement, monitored by Fourier Transform Infrared Spectroscopy (FTIR) and Scanning Electron Microscopy (SEM)

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Summary

Introduction

A series of chemical reactions takes place during the hydration process of cement paste. Once water is added to the cement, the tricalcium aluminate reacts with the gypsum to produce ettringite and heat. The tricalcium silicate is hydrated to produce the C-S-H, lime and heat. Once the gypsum is gone, the ettringite becomes unstable and begins to react with the remaining tricalcium aluminate to form monosulfate aluminate hydrate crystals (Winter, 2012). The first reaction is when the ettringite reacts with the water and gypsum to form ettringite, lime and alumina hydroxides. The second reaction occurs when the ferrite further reacts with the ettringite that was formed during the first reaction in order to produce garnets

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