Abstract
Several Mn and/or Ce oxides on blast furnace slag-derived (BFS-derived) zeolite X catalysts were prepared to investigate their low-temperature NH3-SCR performance. It was found that Mn-Ce/X catalyst had the highest NO conversion of nearly 98% at 250 °C and excellent N2 selectivity of nearly 100% during 75–175 °C. The co-addition of Ce and Mn could inhabit the growth of crystal grains, resulting in the increase of surface area and the generation of Mn-Ce double active sites. Besides, high concentration of Mn4+ and Mn3+ could promote oxidation of NO to NO2 accelerating the “fast-SCR” reaction and high concentration of Ce4+ could form more oxygen vacancies on Mn-Ce/X catalyst. In addition, the Mn-Ce/X catalyst had large acid amount and high redox ability owing to the co-existed Mn-Ce double active sites on zeolite catalyst and the co-effect of Mn-Ce oxides and zeolite X. Furthermore, the decomposition of NH4NO3 species on Mn/X catalyst led to the low N2 selectivity at higher temperature. While NH2NO and NH4NO2 intermediates on Mn-Ce/X catalyst played a vital part in NH3-SCR reaction and prevented the generation of N2O, and Mn-Ce/X catalyst provided more Mn-Ce active sites for the reaction between NO3– species and gaseous NO, accelerating SCR catalytic reaction.
Published Version
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