Effect of mechanical and electro-chemical contacts on the particle orientation of clay minerals during swelling and sedimentation: A DEM simulation

Abstract

The importance and quality of particle orientation on the performance of clay has been well-documented experimentally. This paper aims to quantitatively evaluate clayey mineral reorientation during swelling/sedimentation according to the balance of mechanical contacts and electrochemical forces. A DEM code has been developed and the behavior of montmorillonite, kaolinite and illite, each having different pore fluid characteristics, has been simulated as for platy-shaped particles. Nonlinear contact law was considered for the induced net force as it relates to the mechanical contacts, Van der Waals attractive force, and diffuse double-layer (DDL) repulsive force. Good compatibility was observed between the DEM simulation and DDL theory. The results showed that the particle weight, magnitude of the repulsive force, and number of DDL contacts were effective parameters controlling particle reorientation. At a low swelling pressure, the particles rotated easily such that an edge-to-face fabric was created and the potential for overlap between particles as well as the mechanical contacts increased. The number of the mechanical contacts versus the time of sedimentation was not linear, but bell-shaped. Kaolinite ranked higher on the DDL repulsive contact list; however, it had a higher deposition rate due to its higher particle weight and lower repulsion force.