Effect of magnesium treatment on microstructure and property of H13 die steel during EAF-LF-VD-CC steelmaking process

Abstract

Due to the advantages of Mg on inclusions and carbides in H13 steel, Mg wire was added into industrial ladle after VD process to replace traditional Ca treatment in this paper, which is of great significance for industrial production of H13 steel. This paper focuses on the effects of Mg treatment and traditional Ca treatment on the inclusions, carbides, microstructure and mechanical properties in H13 steel. The results show that feeding Mg wire during EAF→ LF→ VD → CC steelmaking process can ensure the submerged nozzle not being blocked under the condition of continuous casting 15 heats of steel ladle, which means feeding Ca wire can be replaced with Mg wire from the aspect of steelmaking production. The primary carbides in Mg treatment steel are mainly precipitated with MgO or MgAl2O4 as the cores and small in size, while the primary carbides in Ca treatment steel are almost large-size carbides without core. The samples taken from the intermediate ladle show that the primary carbide types are all V-rich, Mo-rich and V–Mo-rich composite, and the size of primary carbides in Mg treatment steel is much smaller than that in Ca treatment steel. Adding Mg is helpful to improve the equiaxed crystal rate of continuous casting ingot. The annealed hot rolling samples show that Mg treatment could interrupt the M23C6 (M = Cr, Fe) chain carbides distributed along the grain boundary. The impact test shows that the dimple fracture surface become small and deep after adding Mg, which improves impact toughness significantly.