Abstract

The effects of initial high humid air-curing, standard water-curing and sealed-curing on thaumasite form of sulfate attack (TSA) of cement based materials were studied. The erosion products after three years attack in 5% MgSO4 solution were analyzed by means of X-ray Diffraction (XRD) and Fourier Transform Infrared Spectroscopy (FTIR). Initial high humid air-curing can delay the TSA of specimens for CaCO3 generated by carbonation and filled in the pores of the specimens, forming a compacted surface and restricting the intrusion of SO42-. In comparison, specimens cured in sealed condition occurred TSA most serious resulting from that large amount of inter-defects in specimens for the lower hydration degree, and SO42- ions could intrude into specimens more easily.

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