Abstract
The viscosity is one of the most important properties of ionic liquids (ILs). To uncover the relationship between structure and viscosity from the molecular level is beneficial to designing the ILs with desired viscosity by choice of different cation and anion. The influence of hydrogen bonds on the viscosity for five pyridine-based ILs, [EPy][OTf], [EPy][NTf2], [BPy][OTf], [BPy][NTf2], and [BPy][BF4], is theoretically studied by combination of molecular dynamics and quantum chemistry. Effect of different alkyl chain lengths, cations, and anions on the viscosity is compared to find the critical item. Besides the molecular structure, the roles of hydrogen bond played in the viscosity are analyzed by various factors.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
