Effect of horizontal insertion of metal wire mesh into the flame on the formation and suppression of soot in acetylene diffusion flame

Abstract

A simple and efficient strategy to suppress soot from acetylene diffusion flames is reported for the first time. Horizontally insertion of metal wire mesh into the acetylene diffusion flame is found to greatly suppress the soot emission. The effects of experimental parameters such as acetylene flow rate, wire mesh height above nozzle (WHAN), material of wire mesh, mesh number, and inner diameter of the burner nozzle on soot suppression in acetylene diffusion flames are investigated. In addition, the collected soot samples are characterized by TEM, HRTEM, XRD, BET and Raman. The soot suppression efficiency can reach 100 % by horizontal insertion of the metal wire mesh in the acetylene diffusion flame. The WHAN has a great influence on the effect of soot suppression. In the first 210 s of horizontally inserting the metal wire mesh into the flame, the total mass of collected soot first decreases and then increases with the increase of WHAN. The minimum total mass of soot is achieved when the normalized WHAN (obtained by dividing the wire mesh height above nozzle by flame height without insertion of the wire mesh) is at 0.1. This position corresponds to the soot particle inception zone of the acetylene diffusion flame. The flame is divided into two parts when the metal wire mesh is horizontally inserted into the flame. The temperature of the flame below the metal wire mesh decreases from 1770 K to 1480 K. The temperature of the flame above the metal wire mesh increases from 1590 K to 1780 K. The soot collected on the metal wire mesh grows into a volcano-shaped carbon (VSC) structure. The results of the schlieren imaging experiments show that this structure can promote the mixing of air and fuel in the lower region of the flame thereby suppressing the formation of soot particles. The soot analysis shows that the horizontal insertion of metal wire mesh into the flame leads to high amorphous feature and low degree of structural order of the soot, which means that the oxidation reactivity of the soot increases.