Effect of high temperature exposure on microstructure, mechanical and tribological properties of cold sprayed NiCoCrAlTaY coatings

Abstract

NiCoCrAlTaY coating is widely used in high temperature oxidation resistance, gas erosion protection and gas path sealing of hot-end parts of aeroengines and gas turbines. In this study, NiCoCrAlTaY coatings were prepared on cobalt-based superalloy substrates by high pressure cold spray technology. The microstructure, mechanical property and tribological behaviors of the coatings before and after thermal exposure at 1050 °C were systemically studied. The results showed that NiCoCrAlTaY coatings with very dense structure could be obtained by high-pressure cold spraying with nitrogen as carrier gas. The coating remained completely intimate with the substrate without any cracking and spalling after thermal exposure at 1050 °C for 500 h. Due to elemental diffusion at high temperatures, the coating formed a four-layer structure, including alumina film on the surface, β-NiAl phase depletion layer near the surface, intermediate layer containing β-NiAl phase and β-NiAl phase depletion layer near the substrate. With the prolongation of thermal exposure at 1050 °C, the thicknesses of β-NiAl phase depletion layers both near the surface and the substrate increased. The thickness and content of the intermediate β-NiAl phase layer decreased gradually during thermal exposure. Besides, the average hardness values of the coating rapidly decreased by about 30 % after thermal exposure at 1050 °C for 5 h. In particular, the hardness of the β-NiAl phase depletion layer near the surface substrate was lower than that of the intermediate area containing β-NiAl phase. Due to the microstructure and hardness evolution, the wear resistance of the coating decreased significantly after thermal exposure. The friction coefficient of the coating increased from 0.2 to 0.5, and the volume wear rate of the thermally exposed coating was about 4.5 times higher than that of the as-sprayed coating. The results of this study provide guidance for design and application of high-performance MCrAlY coatings.