Effect of glass composition on activation energy of viscosity in glass-melting-temperature range

Abstract

In the high-temperature range, where the viscosity (η) of molten glass is <103Pas, the activation energy (B) is virtually independent of temperature (T). Moreover, the coefficient A in the Arrhenius relationship, ln(η)=A+B/T, is nearly independent of melt composition. Hence, the viscosity–composition relationship for η<103Pas is defined by B as a function of composition. Using a database encompassing over 1300 compositions of high-level waste glasses with nearly 7000 viscosity data, we developed mathematical models for B(x), where x is the composition vector in terms of mass fractions of components. In this paper, we present 13 versions of B(x) as first- and second-order polynomials with coefficients for 15 to 39 components, including Others, a component that sums constituents having little effect on viscosity.