Effect of Fe additions on microstructure and mechanical properties in near-eutectic Al–Ce alloys

Abstract

The effects of adding 1 or 3 wt % Fe to a near-eutectic Al–10Ce alloy are investigated in terms of their as-cast and aged microstructures, thermal stability, and creep resistance. A 1 wt% Fe addition forms fine, Chinese-script Al10CeFe2 and Al11Ce3 eutectic phases without loss of microhardness as compared to the Fe-free Al–10Ce alloy, unlike in traditional cast Al-alloys where detrimental coarse phases are observed when adding Fe. Adding 3 wt% Fe increases hardness significantly while forming primary Al10CeFe2 in a coarse rod morphology. These near-eutectic Al–10Ce–1Fe and hyper-eutectic Al–10Ce–3Fe alloys, after thermal exposure at 400 and 425 °C for up to 384 h, show only a small loss in microhardness, indicating excellent coarsening resistance. Compressive creep measurements performed at 300 °C show similar trends: (i) near-eutectic Al–10Ce–1Fe performs quite similarly to near-eutectic Al–10Ce and (ii) hyper-eutectic Al–10Ce–3Fe exhibits much improved creep resistance, similar to near-eutectic Al–10Ce–5Ni with costly Ni additions, and much better than hyper-eutectic Al–13Ce. After surface laser remelting to simulate laser powder-bed fusion, the near-eutectic Al–10Ce–1 Fe alloy exhibits greatly refined Al10CeFe2 and Al11Ce3 eutectic phases with a doubling in microhardness, indicating a strong potential for laser-based additive manufacturing. Cast Al–Ce–Fe-based alloys show great promise as low-cost alloys with high creep- and coarsening-resistance for use at high temperatures, with the high Fe tolerance enabling the use of recycled aluminum with high Fe contamination.