Effect of efficient structural tuning on the microstructure, corrosion resistance, and wear performance of AlCoCrFeNi/AT13 composite coatings

Abstract

This study developed a rapid structure control technique for AlCoCrFeNi/AT13 (Al₂O₃–13 % TiO₂) composite coatings using plasma spraying and dual powder feeding. Four coatings were fabricated: pure HEA, HEA-D (dispersed), HEA-S1 (multilayer with outer HEA), and HEA-S2 (multilayer with outer AT13). The introduction of AT13 altered the internal stress distribution and enhanced corrosion resistance by lowering the electrochemical reaction rate. In layered coatings (HEA-S1, HEA-S2), the AT13 interlayer barrier reduced corrosion tendency. Additionally, pure HEA coatings exhibited adhesive wear. While HEA-D coatings experienced abrasive wear as AT13 particles improved plastic deformation and interface shearing. HEA-S1 reduced strain and wear via an internal AT13 layer. HEA-S2 achieved superior abrasion resistance through an outer AT13 layer, exhibiting typical abrasive wear mechanisms.