Effect of different aggregates on the properties of carbonated self-pulverized low-calcium clinker mortar

Abstract

This study investigated the effects of four aggregates - standard sand, manufactured sand, slag, and coal gangue - on the properties of carbonated self-pulverized low-calcium clinker (SPLCC) mortars. The SPLCC, aggregates, and water were mixed in a mass ratio of 1.00:2.50:0.15 and compaction molded, then carbonation cured by 99.99 % CO2 exposure at 0.2 MPa. Tests determined the weight gain, compressive strength, water absorption, and interfacial transition zone (ITZ) microstructure after 1, 4, and 24 h of curing. Results showed the manufactured sand mortar had the highest compressive strength (39.7 MPa) and lowest water absorption (3.50 %) at 24 h, indicating the best macroscopic performance. This was due to the manufactured sand's stone powder content improving SPLCC binding and accelerating calcium carbonate accumulation in the ITZ. Nanoindentation revealed the manufactured sand mortar had the narrowest ITZ width (15 μm). SEM-BSE also showed higher Ca content in its ITZ. The Ca: Si ratio in the ITZ strongly correlated with strength and absorption. Overall, manufactured sand as aggregate can enhance carbonated SPLCC mortar properties, providing potential for precast products.