Abstract

Deep drying and torrefaction compose a thermal pretreatment method where biomass is heated in the temperature range of 150–300 °C in an inert or reduced environment. The process parameters, like torrefaction temperature and residence time, have a significant impact on the proximate, ultimate, and energy properties. In this study, torrefaction experiments were conducted on 2-mm ground lodgepole pine (Pinus contorta) using a thermogravimetric analyzer. Both deep drying and torrefaction temperature (160–270 °C) and time (15–120 min) were selected. Torrefied samples were analyzed for the proximate, ultimate, and higher heating value. The results indicate that moisture content decreases with increases in torrefaction temperature and time, where at 270 °C and 120 min, the moisture content is found to be 1.15% (w.b.). Volatile content in the lodgepole pine decreased from about 80% to about 45%, and ash content increased from 0.77% to about 1.91% at 270 °C and 120 min. The hydrogen, oxygen, and sulfur content decreased to 3%, 28.24%, and 0.01%, whereas the carbon content and higher heating value increased to 68.86% and 23.67 MJ/kg at 270 °C and 120 min. Elemental ratio of hydrogen to carbon and oxygen to carbon (H/C and O/C) calculated at 270 °C and a 120-min residence time were about 0.56 and 0.47. Based on this study, it can be concluded that higher torrefaction temperatures ≥230 °C and residence time ≥15 min influence the proximate, ultimate, and energy properties of ground lodgepole pine.

Highlights

  • In the recent United Nations Paris Framework Convention on Climate Change (PFCCC), there is a call to mitigate the global annual emissions of greenhouse gases by 2020 in order to reduce the global average temperature increase to less than 2 ̋C [1]

  • The present study indicated that the change in the chemical composition at deep drying temperature (160 and 180 ̋C) is minimal compared to torrefaction temperatures of 230 and 270 ̋C

  • The research presented was carried out to understand the effect of torrefaction temperature and residence time on the proximate composition, ultimate composition, and higher heating values of a 2-mm lodgepole pine grind

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Summary

Introduction

In the recent United Nations Paris Framework Convention on Climate Change (PFCCC), there is a call to mitigate the global annual emissions of greenhouse gases by 2020 in order to reduce the global average temperature increase to less than 2 ̋C [1]. According to the Kyoto Protocol [3], increasing the use of biomass helps to reduce carbon dioxide emissions and to reduce its negative impact on the environment. According to the U.S Department of Energy (DOE) [4], about a billion tons of biomass is available in the United States for energy applications. This enhances the ability of the United States to include biomass as a sustainable and significant part of domestic energy production

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