Abstract
Abstract Different conjugated 2D-side groups were introduced to polymerize four types of two-dimensional polymers, PQCT-m8Qx, PQCT-mEHQx, PQCT-BT and PQCT-DPP, through a Suzuki coupling reaction. In comparison with the linear polymer which used the same backbone, the two-dimensional (2D) conjugated side chain polymer exhibits the delocalization of its electron clouds due to the extension of the side chain. So, all four polymers showed a low HOMO level, thus showing high VOC. Among the four, the HOMO level of PQCT-BT was the lowest, by −5.63 eV. When manufacturing a device, VOC was 0.92 V, which is the highest.
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