Effect of colemanite on properties of traditional mullite zirconia composite

Abstract

AbstractIn this study, mullite zirconia composites are synthesized via reaction sintering method by using zircon, kaolinite and alumina mixtures including colemanite (Ca2B6O115H2O) (7 wt.%). In mullite zirconia composites, the effect of colemanite additive on mineralogical, thermal, microstructure and mechanical properties and also on formation are studied. Mixtures are sintered at 1,450, 1,500 and 1,550°C for 5 h. in air. The resulting sintered materials are characterized in terms of bulk density, DTA, X-ray diffraction (XRD), SEM and mechanical properties such as flexural strength and elastic modulus. Various effects of colemanite addition on the composites are observed with regard to thermal, mineralogical and mechanical properties. Both DTA and XRD analyses show that colemanite addition in mullite zirconia composite reduces the reaction temperature. Zircon alone in the mixture resulted in a 1,550°C reaction temperature, whereas the compositions including colemanite is attenuated to 1,450°C. While zirc...