Abstract
The thermodynamic interactions in poly(styrene-block-ferrocenyldimethylsilane) and poly(isoprene-block-ferrocenyldimethylsilane) copolymers were systematically tuned by oxidation of the ferrocene moieties with silver nitrate. Small-angle X-ray scattering experiments show that oxidizing 8% of the ferrocene moieties lowers the order-disorder transition temperature of the copolymers by as much as 40 degrees C.
Published Version
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