Effect of chemical composition of coal ash used to prepare granulated coal ash on the removal of hydrogen sulfide from water.

Abstract

Granulated coal ash was prepared by mixing coal ash derived from a coal electric power plant and blast furnace cement, to remove hydrogen sulfide from aquatic environment. In this study, we investigate the effects of the composition of the coal ash used to prepare the granulated coal ash on its hydrogen sulfide removal performance. Manganese, magnesium, and calcium contents in the granulated coal ash were found to be the major factors in controlling the rate of hydrogen sulfide removal. The kinetics of hydrogen sulfide removal by the granulated coal ash were expressed as a first-order equation with a rate constant of 0.0081- 0.080 h-1 . The rate constant for hydrogen sulfide removal obtained in this study corelated well with the manganese content in the granulated coal ash. The increasing surface pH attributed to the hydrolysis of calcium and magnesium on the surface of the granulated coal ash slightly increased the hydrogen sulfide removal rate.