Effect of CASP glass doping on sintering and dielectric properties of SBN ceramics

Abstract

16CaO–29Al 2O 3–34SiO 2–13PbO–4B 2O 3–2ZnO–2P 2O 5 (CASP) glass doped-Sr 0.5Ba 0.5Nb 2O 6 (SBN50) ceramics have been synthesized by solid-state ceramic route. The effects of CASP glass on the firing, microstructure and dielectric characterization of SBN50 ceramics are investigated. The densities of the ceramic samples firstly increase and then slightly decrease with increasing CASP glass content. The appropriate amount of doping glass is 2%. The SBN50 ceramics doped with CASP glass can be sintered at a relatively low temperature, 1200 °C. X-ray diffraction analysis shows the single phase (tetragonal tungsten bronze type structure) is preserved for all the samples. The diffuse character of the ceramic system increases and the dielectric constant at phase transition temperature ( T c) markedly decreases as CASP glass content increases. Interestingly, the CASP glass addition drastically alters the microstructure of the sintered ceramics. The isotropic grains in the pure SBN50 ceramics transform to rod like grains after the addition of CASP glass. The grain size of SBN phase is found to obviously increase with increase in CASP glass doping level.