Effect of blowing agent concentration of ultra‐low density NBR/PVC composite foams on compressive behavior and energy‐absorption characteristics

Abstract

AbstractUltra‐low density nitrile butadiene rubber (NBR)/polyvinyl chloride (PVC) composite foams that exhibit satisfactory compressive behavior and energy absorption characteristics were prepared by one‐step compression molding. The properties of the NBR/PVC foams, including the density, hardness, cell morphology, compressive behavior, energy absorption characteristics, and shock absorption characteristics, were studied with various concentrations of azodicarbonamide (AC). Further that, the ideality factor and the energy absorption efficiency of the NBR/PVC foams at a low stress for application in compression and energy absorption were determined. The results revealed that the densities of polymeric foams were crucial in determining the uniformity of cell size and energy absorption characteristics of the composite foams. With increasing AC content, the density of the NBR/PVC foams decreased linearly, whereas the uniformity of cell size and the foaming ratio increased; furthermore, the hardness and compression modulus gradually decreased, and the linear elastic region in the compressive stress–strain curves became narrow. When the applied stress was less than 100 kPa, the foams with a high AC content exhibited higher energy absorption compared to foams with a low AC content capacity because of the deformed cell wall and lower elastic modulus; however, the relation between AC contents and energy absorption was complicated above 100 kPa. The optimum springrate ratio was found at the concentration of 25 phr of the AC blowing agent.