Abstract
Flow-injection measurements were performed using chloride, fluoride, iodide and copper(II)-selective electrodes. A pronounced effect of addition of main ion to the carrier solution was observed for the fluoride- and iodide-selective electrode. Super-Nernstian slope observed for the fluoride- and copper(II)-selective electrode in the absence of the sensed ion in the carrier solution decreased to Nernstian values in the presence of the measured ion in the carrier solution. This phenomenon is explained by different response times at different concentrations of the sensed ion.
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