Ecological risk assessment of trace metals in sediment from the Old Brahmaputra River in Bangladesh

Abstract

ABSTRACT The assessment of trace metal contamination in river sediments is crucial for suggesting effective strategies to protect aquatic ecosystem health. In this study, six toxic trace metals (As, Cd, Cr, Hg, Ni and Pb) in the surface sediments from the Old Brahmaputra River in Bangladesh were examined to evaluate the potential ecological risks. Sediment samples were collected in September 2018 and analysed by an atomic absorption spectrometer. Mean concentrations (mg/kg dw) of trace metals were in the order of Ni (43.49) > Cr (30.25) > Pb (14.29) > As (3.74) > Hg (0.16) > Cd (0.03). Spatially the sedimentary metals did not vary significantly. Source analyses revealed anthropogenic origin for most of the metals. The contamination factor, enrichment factor and geoaccumulation index (I geo) revealed a low degree of contamination for all cases except Hg, which showed a moderate degree of contamination. According to the sediment quality guidelines and sediment screening values, only Cr, Hg and Ni were high enough to cause detrimental effects in aquatic organisms. The potential ecological risk factor (Er i ) and potential ecological risk also revealed low to moderate ecological risk. Comprehensively, the river was in the uncontaminated to moderately contaminated level with low ecological risk.