Echo modulations under homonuclear decoupling

Abstract

A simple Hahn echo in a single-spin system with a static Hamiltonian can lead to echo modulations if the static Hamiltonian contains a component along the direction of the echo pulse. These modulations manifest as side bands in the Fourier transform of the echo decay. Experimentally, echo modulations that can be explained by such a model have been observed under homonuclear decoupling in solids where pulse imperfections can lead to residual effective fields in the interaction frame that have arbitrary orientations in space. We show analytically that such echo modulations are significantly reduced in intensity using double-echo sequences in agreement with experimental observations. Using pulse shapes for homonuclear decoupling that mimic and amplify the pulse distortions expected from pulse transients, we show that these effective fields can be one explanation for the observed reduction in echo modulations going from a single to a double Hahn-echo sequence.