Abstract

(η 5-C 5H 5) 2M[Co(CO) 4] 2 (MTi, Zr) complexes were prepared by alkane elimination from the corresponding metallocene diorganyls and HCo(CO) 4 or by salt elimination from metallocene dihalides and Na[Co(CO) 4]. (Ph 2N) 2Ti[Co(CO) 4] 2 was obtained from (Ph 2N) 4Ti and HCo(CO) 4.

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