Dynamics of a rate equation describing cluster-size evolution

Abstract

In this paper, we show dynamics of Smoluchowski's rate equation which has been widely applied to studies of aggregation processes (i.e., the evolution of cluster-size distribution) in physics. We introduce dissociation in the rate equation while dissociation is neglected in previous works. We prove the positiveness of solutions of the equation, which is a basic guarantee for the effectiveness of the model since the possibility that some solution may be negative is excluded. For the case of cluster coalesce without dissociation, we show both the equilibrium uniqueness and the equilibrium stability under the condition that the monomer deposition stops. For the case that clusters evolve with dissociation and there is no monomer deposition, we show the equilibrium uniqueness and prove the equilibrium stability if the maximum cluster size is not larger than three while we show the equilibrium stability by numerical simulations if the maximum size is larger than three.