Abstract
The Auger emission following the resonant excitation of the BCl3 molecule has been investigated using monochromatized synchrotron radiation. The B 1s excitation to the unoccupied Anti-bonding 4e(') orbital enhances the shoulder structure in the low kinetic energy side of the photoemission from the 2e(') valence bonding orbital. Based on a series of quantum mechanical calculations, this shoulder structure is interpreted as the dynamical Auger emission which reflects the B-Cl stretching nuclear motion and appears as a result of the purely multistate vibronic coupling effect among the Jahn-Teller split B 1s(-1)4e(') E' states and the closely lying B 1s(-1)3a(')(1) A'1 state.
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