Abstract

The selective catalytic reduction (SCR) decomposition of nitrogen oxide (de-NOx) process in coal-fired power plants not only displays nonlinearity, large inertia and time variation but also a lag in NOx analysis; hence, it is difficult to obtain an accurate model that can be used to control NH3 injection during changes in the operating state. In this work, a novel dynamic inferential model with delay estimation was proposed for NOx emission prediction. First, k-nearest neighbour mutual information was used to estimate the time delay of the descriptor variables, followed by reconstruction of the phase space of the model data. Second, multi-scale wavelet kernel partial least square was used to improve the prediction ability, and this was followed by verification using benchmark dataset experiments. Finally, the delay time difference method and feedback correction strategy were proposed to deal with the time variation of the SCR de-NOx process. Through the analysis of the experimental field data in the steady state, the variable state and the NOx analyser blowback process, the results proved that this dynamic model has high prediction accuracy during state changes and can realize advance prediction of the NOx emission.

Highlights

  • During the operation of coal-fired power plants, NOx emissions discharged into the atmosphere via the exhaust gas are very royalsocietypublishing.org/journal/rsos R

  • To improve the accuracy of the NOx emission prediction model and solve the time-varying problem for the selective catalytic reduction (SCR) decomposition of nitrogen oxide (de-NOx) process, a novel dynamic inferential model is proposed in this paper

  • Assuming that the NOx analyser is in the blowback process from t = 300 min to t = 350 min and the model configuration parameters are L = 4, cà = 2, a1 = 2 and a2 = 18, the results show that the dynamic model can still maintain high accuracy, as seen from figure 7 and table 9; the deviation between the predicted value and the real value is small, which effectively tracks the change in the curve, even for the highest or lowest points

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Summary

Introduction

During the operation of coal-fired power plants, NOx emissions discharged into the atmosphere via the exhaust gas are very royalsocietypublishing.org/journal/rsos R. To improve the accuracy of the NOx emission prediction model and solve the time-varying problem for the SCR de-NOx process, a novel dynamic inferential model is proposed in this paper.

Theory
Kernel partial least square model
Calculate the score vector ui ui
Data preprocessing
Delay estimation and model samples reconstruction
Multi-scale wavelet kernel partial least square
Dynamic model update method
Framework for the dynamic inferential model
Benchmark dataset experiments
SCR de-NOx process
The selection of model variables and samples
Analysis of the data preprocessing results
Analysis of the delay estimation result
Data correlation analysis
Analysis of knnMI-mwKPLS model parameters
Dynamic inferential model analysis
Conclusion
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