Abstract
The effects of anode composition and temperature on anode electrochemical properties, the passivation layer’s structure, and ferrate(VI) generation in 14 M NaOH were investigated. Cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS), and galvanostatic polarization (GP) were used to analyze the electrochemical processes involving the electrosynthesis of ferrate using some low-cost anode materials: ductile iron, grey cast iron, and mild steel. The results proved that the presence of silicon and graphite with sphere form in the ductile iron anode significantly increased ferrate electro-generation. The optimal temperature for the electro-generation of ferrate was 30 °C–40 °C. The current efficiency using the ductile iron anode was constantly at least about 30% superior to that of the grey cast iron and mild steel electrodes. The ductile iron anode material was the most feasible option because it provides the highest ferrate concentration (1.58 g L−1) with the highest current efficiency of 74% and the lowest specific energy consumption of 1.2 kWh kg−1 ferrate.
Published Version
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