Abstract
Recently, Warren and co-workers have shown that double quantum, gradient selective, 2D NMR experiments can give rise to apparently unreconcilable double quantum signals and intermolecular cross peaks. These experiments have been used to challenge the basic assumptions of room temperature NMR. We re-examine the gradient-induced multiple spin echo explanation, first discussed by Warren. It is shown that simple analytical explanations can be provided for (i) double quantum peaks, (ii) cross correlation peaks, (iii) the amplitudes of the observed cross peaks, and (iv) the disappearance of the cross peaks when the solvent and solute are placed in different tubes.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
