Abstract
Whopper sandwich: A double-decker ferrocene-type complex with N-fused porphyrinato ligands (see picture) was synthesized from N-fused porphyrin, and its structure and properties were characterized with X-ray crystallographic analysis, variable-temperature 1H NMR spectra, and electrochemical measurements. The unique three-dimensional d–π conjugated system was elucidated with the aid of DFT studies.
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