Abstract

Abstract Such imidazolium methylides as imidazolium dicyanomethylide and bis(ethoxycarbonyl)methlide react with the methylenecyclopropenes with unsaturated substituents at the 4-position in the fashion of double cycloaddition reaction, leading to the novel cage compounds, which involves an intermorecular 1,3-dipolar cycloaddition reaction and an intramolecular Diels-Alder reaction.

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