Abstract
SynopsisIn recent years double core-hole states are intensively studied since their chemical shifts provide detailed information about initial-state and relaxation effects in a molecule. We derived the Si 1s−1, 2s−1, and 2p−1 binding energies as well as the Si 2s−2, 2s−1, 2p−1, and 2p−2 double-core hole binding energies of different SiX4 systems in order to derive the chemical shifts. Based on these results we created Wagner plots, which give insight in the initial state and the relaxation effects in the different molecules.
Highlights
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not
Double core-hole states in SiX4 (X = F, Cl, Br, and CH3) molecules derived by photoelectron and KLL Auger spectroscopy
In recent years double core-hole states are in- core hole state, which give a detailed insight in tensively studied since their chemical shifts pro- the initial state and relaxation effects [4]
Summary
HAL is a multi-disciplinary open access archive for the deposit and dissemination of scientific research documents, whether they are published or not. Double core-hole states in SiX4 (X = F, Cl, Br, and CH3) molecules derived by photoelectron and KLL Auger spectroscopy This content has been downloaded from IOPscience. Ser. 635 112057 (http://iopscience.iop.org/1742-6596/635/11/112057) View the table of contents for this issue, or go to the journal homepage for more
Sign-in/Register to view highlights & summary 
Published Version (
Free)
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a call