Dominant Aggregate Binding Agent Dynamics of Quaternary Ancient Red Soils under Different Land Use Patterns

Abstract

The cementation mechanisms and processes of aggregate binding agents are important in understanding aggregate formation. However, the role of threshold values and the proportions of organic and inorganic binding agents in aggregate formation remain unclear. This research investigated the dominant aggregate binding agent dynamics in a sequence comprising buried ancient red soil unaffected by modern climate changes and human activities, alongside nearby exposed Quaternary ancient red soils subjected to different land use patterns influenced by these factors in northeastern China. By analyzing soil age, aggregate compositions, and organic/inorganic indicators of binding agents, including soil organic matter (SOM), free iron oxide (Fed), poorly crystalline iron oxide (Feo), crystalline iron oxide (Fed-Feo), and total clay particles (TCL), we determined the relative contributions of different binding agents using redundancy analysis (RDA). The results revealed that the buried ancient red soil did not contain dominant binding agents in the aggregate formation before 91.01 ka BP. Due to denudation, the buried ancient red soil was exposed at the surface and experienced the importation of soil organic matter, weathering of silicate-bound iron oxides, and crystallization of poorly crystalline iron oxides resulting from the effects of different land use patterns from 91.01 ka to the present. Under the influence of binding agent dynamics, dominant binding agents in the exposed Quaternary ancient red soils’ aggregate formation changed into SOM and Fed. When the C/(Fed-Feo) molar ratio was less than 2.13, Fed-Feo was the dominant aggregate binding agent. When the C/(Fed-Feo) molar ratio was greater than 2.13, SOM was the dominant aggregate binding agent. The results of this study improve our understanding of aggregate formation and the relationship between soil organic matter and iron oxides.