Abstract

The stoichiometric Nd 2NiO 4 compound presents two structural phase transitions. A high-temperature transformation from tetragonal I4/mmm to orthorhombic Bmab and a low-temperature transition from orthorhombic to another tetragonal structure, P4 2/ncm. Associated with this second phase transition there is a strong microstrain effect that produces anisotropic broadening of the Bragg reflections. The effect of hydrostatic pressure in this compound has been studied, showing that the critical temperature of the low-temperature phase transition is greatly diminished and the fluctuation of the lattice parameters becomes bigger. On the contrary, pressure does not seem to affect magnetic ordering.

Full Text
Published version (Free)

Talk to us

Join us for a 30 min session where you can share your feedback and ask us any queries you have

Schedule a call